72262
Nickel (IV) oxide
technical, ~30% active peroxide basis
Synonym(s):
Nickel dioxide, Nickel oxide
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About This Item
Empirical Formula (Hill Notation):
NiO2
CAS Number:
Molecular Weight:
90.69
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352000
EC Number:
234-823-3
MDL number:
InChI key
PZFKDUMHDHEBLD-UHFFFAOYSA-N
InChI
1S/2Ni.3O
SMILES string
O=[Ni]O[Ni]=O
grade
technical
form
powder
reaction suitability
core: nickel, reagent type: catalyst, reagent type: oxidant
concentration
~30% (active peroxide)
Quality Level
Application
Catalyst for:
Used to study differences in reactivity trends for carbon monoxide catalyzed oxidation caused by anionic transition metal oxide clusters
Reagent:
- One-dimensional oxide-metal hybrid structures and site-specific enhanced reactivity for CO oxidation
- Microwave induced catalytic degradation of crystal violet
Used to study differences in reactivity trends for carbon monoxide catalyzed oxidation caused by anionic transition metal oxide clusters
Reagent:
- For solvent-free oxidation of alcohols†
- For chemoselective oxidation of organic compounds using inductive heating
- To improve the synthesis of methoxy cephalosporin′s intermediate
Other Notes
Oxidant for the transformation of alcohols into acids and hydrazones into diazoalkanes
signalword
Danger
Hazard Classifications
Aquatic Chronic 4 - Carc. 1A Inhalation - Ox. Sol. 2 - Skin Sens. 1 - STOT RE 1 Inhalation
Storage Class
5.1B - Oxidizing hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Shadabul Haque et al.
Journal of controlled release : official journal of the Controlled Release Society, 307, 32-43 (2019-06-04)
The development of inhalable 'nanomedicines' based on biocompatible lipids and polymers is attracting increasing interest worldwide. Our understanding of how pulmonary inflammation impacts on lung distribution and clearance kinetics however, is limited. Similarly, there is limited information on how the
Javier Jiménez-Lamana et al.
Nanomaterials (Basel, Switzerland), 10(5) (2020-05-28)
Although nickel allergy and carcinogenicity are well known, their molecular mechanisms are still uncertain, thus demanding studies at the molecular level. The nickel carcinogenicity is known to be dependent on the chemical form of nickel, since only certain nickel compounds
K. Nakagawa et al.
The Journal of Organic Chemistry, 27, 1597-1597 (1962)
Rut Sanchis et al.
Materials (Basel, Switzerland), 12(18) (2019-09-12)
Different nickel catalysts have been tested for the transformation of levulinic acid into γ-valerolactone using an easy hydrothermal method, taking advantage of the properties of the high temperature water. A metallic nickel catalyst derived from NiO synthesized by a nanocasting
Zachary Daniels et al.
Materials (Basel, Switzerland), 12(18) (2019-09-11)
Described herein is a novel method, Reduction Expansion Synthesis-Sintered Metal (RES-SM), to create a sintered metal body of a designed shape at ambient pressure, hundreds of degrees below the metal melting temperature. The precursor to the metal part is a
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