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Merck
CN

72262

Nickel (IV) oxide

technical, ~30% active peroxide basis

Synonym(s):

Nickel dioxide, Nickel oxide

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About This Item

Empirical Formula (Hill Notation):
NiO2
CAS Number:
12035-36-8
Molecular Weight:
90.69
NACRES:
NA.22
PubChem Substance ID:
57652407
UNSPSC Code:
12352000
EC Number:
234-823-3
MDL number:
MFCD00011143

Key Documents

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Product Name

Nickel (IV) oxide, technical, ~30% active peroxide basis

InChI key

PZFKDUMHDHEBLD-UHFFFAOYSA-N

InChI

1S/2Ni.3O

SMILES string

O=[Ni]O[Ni]=O

grade

technical

form

powder

reaction suitability

core: nickel
reagent type: catalyst
reagent type: oxidant

concentration

~30% (active peroxide)

Quality Level

100

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Application

Catalyst for:
  • One-dimensional oxide-metal hybrid structures and site-specific enhanced reactivity for CO oxidation
  • Microwave induced catalytic degradation of crystal violet

Used to study differences in reactivity trends for carbon monoxide catalyzed oxidation caused by anionic transition metal oxide clusters

Reagent:
  • For solvent-free oxidation of alcohols†
  • For chemoselective oxidation of organic compounds using inductive heating
  • To improve the synthesis of methoxy cephalosporin′s intermediate

Other Notes

Oxidant for the transformation of alcohols into acids and hydrazones into diazoalkanes

signalword

Danger

Hazard Classifications

Aquatic Chronic 4 - Carc. 1A Inhalation - Ox. Sol. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
BCCN7776
BCCM0317
BCCH7610
BCBZ5530
BCBQ0423V

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Shadabul Haque et al.
Journal of controlled release : official journal of the Controlled Release Society, 307, 32-43 (2019-06-04)
The development of inhalable 'nanomedicines' based on biocompatible lipids and polymers is attracting increasing interest worldwide. Our understanding of how pulmonary inflammation impacts on lung distribution and clearance kinetics however, is limited. Similarly, there is limited information on how the
Javier Jiménez-Lamana et al.
Nanomaterials (Basel, Switzerland), 10(5) (2020-05-28)
Although nickel allergy and carcinogenicity are well known, their molecular mechanisms are still uncertain, thus demanding studies at the molecular level. The nickel carcinogenicity is known to be dependent on the chemical form of nickel, since only certain nickel compounds
Robert K DeLong et al.
Nanomaterials (Basel, Switzerland), 9(12) (2019-11-28)
Currently, there is a great interest in nanoparticle-based vaccine delivery. Recent studies suggest that nanoparticles when introduced into the biological milieu are not simply passive carriers but may also contribute immunological activity themselves or of their own accord. For example
Chiara Argentati et al.
Journal of personalized medicine, 10(1) (2020-02-12)
Ex vivo cell/tissue-based models are an essential step in the workflow of pathophysiology studies, assay development, disease modeling, drug discovery, and development of personalized therapeutic strategies. For these purposes, both scientific and pharmaceutical research have adopted ex vivo stem cell
Rut Sanchis et al.
Materials (Basel, Switzerland), 12(18) (2019-09-12)
Different nickel catalysts have been tested for the transformation of levulinic acid into γ-valerolactone using an easy hydrothermal method, taking advantage of the properties of the high temperature water. A metallic nickel catalyst derived from NiO synthesized by a nanocasting
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