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Merck
CN

723223

Dodecyl 2-bromoisobutyrate

Synonym(s):

Dodecyl initiator

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About This Item

Empirical Formula (Hill Notation):
C16H31BrO2
CAS Number:
934001-46-4
Molecular Weight:
335.32
UNSPSC Code:
12162002
PubChem Substance ID:
329763988
MDL number:
MFCD16621497

Key Documents

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InChI

1S/C16H31BrO2/c1-4-5-6-7-8-9-10-11-12-13-14-19-15(18)16(2,3)17/h4-14H2,1-3H3

SMILES string

CCCCCCCCCCCCOC(=O)C(C)(C)Br

InChI key

TUPZPNIRCIQNLF-UHFFFAOYSA-N

form

liquid

refractive index

n20/D 1.455

density

1.058 g/mL at 25 °C

Application

Atom Transfer Radical Polymerization (ATRP) initiator for the creation of dodecyl functionalized telechelic polymers.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBG7788
MKBG7788V

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Atom transfer radical polymerization.
K Matyjaszewski et al.
Chemical reviews, 101(9), 2921-2990 (2001-12-26)
Coessens, V.; Pintauer, T.; Matyjaszewski, K.
Progress in Polymer Science, 26, 337-337 (2001)
"Green" atom transfer radical polymerization: from process design to preparation of well-defined environmentally friendly polymeric materials.
Nicolay V Tsarevsky et al.
Chemical reviews, 107(6), 2270-2299 (2007-05-29)

Articles

ATRP Ligands & Initiators: Clean Functional Polymers

ATRP is a successful method for precise polymer synthesis with controlled molecular weights and high chain end functionalities.

Protocols

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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