725285
(Iodomethyl)triphenylphosphonium iodide
95%
Synonym(s):
NSC 116665
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About This Item
Empirical Formula (Hill Notation):
C19H17I2P
CAS Number:
Molecular Weight:
530.12
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
MDL number:
Assay:
95%
Form:
solid
InChI
1S/C19H17IP.HI/c20-16-21(17-10-4-1-5-11-17,18-12-6-2-7-13-18)19-14-8-3-9-15-19;/h1-15H,16H2;1H/q+1;/p-1
SMILES string
[I-].IC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI key
NAVMMSRRNOXQMJ-UHFFFAOYSA-M
assay
95%
form
solid
reaction suitability
reaction type: C-C Bond Formation
mp
260-266 °C
functional group
iodo, phosphine
Application
Reactant or reagent for synthesis of:
Reactant for vinylcyclopropanation / cyclopentenation of strained alkenes using a sequential carborhodation process
Used as an olefination agent in the Lewis acid catalysis of electrocyclization of trienes
- Phosphacyclic compounds via oxidative dimerizations
- Enamides via cross-coupling
- Cyclopeptide alkaloids for use as antibacterial or cytotoxic agents
- Terminal alkynes via dehydrohalogenation of aldehydes
Reactant for vinylcyclopropanation / cyclopentenation of strained alkenes using a sequential carborhodation process
Used as an olefination agent in the Lewis acid catalysis of electrocyclization of trienes
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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