726842
(R)-(+)-4-Methoxy-α-methylbenzylamine
ChiPros®, produced by BASF, 99%
Synonym(s):
(R)-(+)-1-(4-Methoxyphenyl)ethylamine
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About This Item
Empirical Formula (Hill Notation):
C9H13NO
CAS Number:
Molecular Weight:
151.21
UNSPSC Code:
12352112
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2413029
Assay:
≥98.5% (GC), 99%
Form:
liquid
Quality Level
assay
≥98.5% (GC), 99%
form
liquid
optical purity
enantiomeric excess: ≥98.5%
density
1.024 g/mL at 20 °C (lit.)
functional group
amine
SMILES string
COc1ccc(cc1)[C@@H](C)N
InChI
1S/C9H13NO/c1-7(10)8-3-5-9(11-2)6-4-8/h3-7H,10H2,1-2H3/t7-/m1/s1
InChI key
JTDGKQNNPKXKII-SSDOTTSWSA-N
Application
(R)-(+)-4-Methoxy-α-methylbenzylamine can be used as a reactant to prepare:
- Enantiopure stereoisomers of hemicryptophanes, which are used for the recognition of glucopyranosides.
- Bicyclic Geissman-Waiss lactone via intramolecular ring-closure reaction of the diastereomeric mixture of sulfonium salts.
- N-[(1R)-1-(4-Methoxyphenyl)ethyl]-N′-methylthiourea by reacting with methyl isothiocyanate.
Legal Information
ChiPros is a registered trademark of BASF SE
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1A
Storage Class
8A - Combustible corrosive hazardous materials
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.
Improved hemicryptophane hosts for the stereoselective recognition of glucopyranosides
Schmitt A, et al.
Organic & Biomolecular Chemistry, 12(24), 4211-4217 (2014)
Synthesis of (+)-and (-)-Geissman-Waiss lactone from chiral sulfonium salts
Lopez-Gonzalez R, et al.
Tetrahedron Letters, 12(24), 151697-151697 (2020)
Yohan Park et al.
Archives of pharmacal research, 35(8), 1393-1401 (2012-09-04)
Thirty two thiourea derivatives were prepared and their agonistic activities on the retinoic acid receptor-related orphan receptor α (RORα) were evaluated. The replacement of the 3-allyl-2-imino-thiazolidin-4-one moiety of the lead compound CGP52608 (1) with various functional group substituted aromatic rings
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 726842-25G | 04061832720005 |
| 726842-100G | 04061832719993 |
| 726842-5G | 04061832720012 |