727733
[2,6-Bis[(di-1-piperidinylphosphino)amino]phenyl]palladium(II) chloride
≥98.0% (AT)
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About This Item
Empirical Formula (Hill Notation):
C26H45ClN6P2Pd
CAS Number:
Molecular Weight:
645.50
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
assay
≥98.0% (AT)
form
lumps
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
SMILES string
Cl[Pd]c1c(NP(N2CCCCC2)N3CCCCC3)cccc1NP(N4CCCCC4)N5CCCCC5
InChI
1S/C26H45N6P2.ClH.Pd/c1-5-16-29(17-6-1)33(30-18-7-2-8-19-30)27-25-14-13-15-26(24-25)28-34(31-20-9-3-10-21-31)32-22-11-4-12-23-32;;/h13-15,27-28H,1-12,16-23H2;1H;/q;;+1/p-1
InChI key
CSXBAGCRLXPPDX-UHFFFAOYSA-M
Application
Palladium catalyst for CC coupling reactions
- Performs Suzuki reactions at low loadings
- High activity at ppm levels for Heck reactions and Sonogashira couplings
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
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Bolliger, J. L. and Frech,C. M.,
Advanced Synthesis & Catalysis, 352, 1075-1080 (2010)
Short, facile, and high-yielding synthesis of extremely efficient pincer-type suzuki catalysts bearing aminophosphine substituents.
Jeanne L Bolliger et al.
Angewandte Chemie (International ed. in English), 46(34), 6514-6517 (2007-07-27)
Bolliger, J. L. and Frech,C. M.
Advanced Synthesis & Catalysis, 351, 891-902 (2009)