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Merck
CN

729078

3,4-Ethylenedithiothiophene

Synonym(s):

3,4-Ethylenedithiothiophene, 2,3-Dihydrothieno[3,4-b][1,4]dithiine, 3,4-Ethylenedisulfanylthiophene, EDTT

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About This Item

Empirical Formula (Hill Notation):
C6H6S3
CAS Number:
Molecular Weight:
174.31
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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InChI

1S/C6H6S3/c1-2-9-6-4-7-3-5(6)8-1/h3-4H,1-2H2

SMILES string

C1CSc2cscc2S1

InChI key

HPGNGICCHXRMIP-UHFFFAOYSA-N

form

liquid

refractive index

n20/D 1.685

density

1.374 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

General description

3,4-Ethylenedithiothiophene (EDTT) is a dithiin based conducting polymer that is a sulfur analog of 3,4-ethylendioxythiophene (EDOT) that is majorly used in optoelectronic and electrochemical devices.

Application

EDTT can be electrochemically oxidized in acetonitrile to form poly(EDTT) films on the surface of the electrodes, which can be used in the fabrication of organic light emitting diodes (OLEDs) and organic photovoltaics (OPVs).

pictograms

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signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

10 - Combustible liquids

wgk

WGK 3

flash_point_f

221.0 °F

flash_point_c

105 °C

Regulatory Information

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Mathieu, T.; et al.
Macromolecules, 38, 6806-6812 (2005)
Redox doping behaviour of poly (3, 4-ethylenedithiothiophene)-The counterion effect.
Domagala W, et al.
Optical Materials, 33(9), 1405-1409 (2011)
Functionalized 3, 4-ethylenedithiathiophenes (EDTTs) as building blocks for poly (3, 4-ethylenedithiathiophene)(PEDTT) derivatives.
Blanco R, et al.
Tetrahedron Letters, 49(13), 2056-2059 (2008)
Randriamahazaka, H.; Sini, G.; Tran Van, F.
The Journal of Physical Chemistry C, 111, 4553-4560 (2007)
Electrosynthesis of poly (3, 4-ethylenedithiathiophene) in an ionic liquid and its electrochemistry and electrochromic properties.
Lu B, et al.
Electrochimica Acta, 106(9), 201-208 (2013)

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