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Merck
CN

730416

S-(α-Fluorobenzyl)-S-phenyl-N-(p-tolylsulfonyl)sulfoximine

97%

Synonym(s):

N-[(fluorophenylmethyl)oxidophenyl-λ4-sulfanylidene]-4-methyl-benzenesulfonamide

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About This Item

Empirical Formula (Hill Notation):
C20H18FNO3S2
CAS Number:
1260143-68-7
Molecular Weight:
403.49
NACRES:
NA.22
PubChem Substance ID:
329764564
UNSPSC Code:
12352101
MDL number:
MFCD18910698
Assay:
97%
Form:
solid

Key Documents

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InChI

1S/C20H18FNO3S2/c1-16-12-14-19(15-13-16)27(24,25)22-26(23,18-10-6-3-7-11-18)20(21)17-8-4-2-5-9-17/h2-15,20H,1H3

SMILES string

Cc1ccc(cc1)S(=O)(=O)N=S(=O)(C(F)c2ccccc2)c3ccccc3

InChI key

ZAGQEXRRSCLLFW-UHFFFAOYSA-N

assay

97%

form

solid

mp

148-154 °C

Application

S-(α-Fluorobenzyl)-S-phenyl-N-(p-tolylsulfonyl)sulfoximine can be used as a reagent for the synthesis of monofluorinated epoxides byO-cyclization reaction with ketones in the presence of a strong base.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class

13 - Non Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBF7464V
MKBF7464

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Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from α-Fluorosulfoximines
Zhang W and Hu J
Advanced Synthesis & Catalysis, 352(16), 2799-2804 (2010)
Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from α-Fluorosulfoximines
Zhang W and Hu J
advanced synthesis and catalysis, 352(16), 2799-2804 (2010)
Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from a-Fluorosulfoximines
Zhang, W.; Hu, J.
Advanced Synthesis & Catalysis, 352, 2799-2804 (2010)

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