730459
(2S,2′S-(−)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate
Synonym(s):
Fe(S,S-PDP), Iron(II) (S,S-(2-({(S)-2-[(S)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate, White Catalyst, [Fe(S,S-PDP)(CH3CN)2](SbF6)2
Select a Size
About This Item
form
powder
Quality Level
optical activity
[α]20/D −30.0 to −20.0°, c = 0.2 in acetonitrile
reaction suitability
core: iron, reagent type: catalyst
reaction type: C-H Activation
mp
>300 °C
SMILES string
[Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4
InChI
1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1
InChI key
XUNWHBGEOCZDBX-QSKJABRXSA-B
Application
Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation
- Oxidative radical reactions
- Selective oxidation of alkyl carbon-hydrogen bonds
- Methylene group oxidation
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
This item has
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.