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Merck
CN

73470

(RP,R′P)-1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(S)-α-(dimethylamino)benzyl]ferrocene

≥97%

Synonym(s):

(1S,1′S)- 1,1′-Bis[bis(4-methoxy-3,5-dimethylphenyl)phosphino]-2,2′-bis[(S)-(dimethylamino)phenylmethyl]ferrocene (acc to CAS), Mandyphos SL-M004-2

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About This Item

Empirical Formula (Hill Notation):
C64H74FeN2O4P2
CAS Number:
Molecular Weight:
1053.08
UNSPSC Code:
12352005
PubChem Substance ID:
MDL number:
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InChI

1S/2C32H37NO2P.Fe/c2*1-21-17-26(18-22(2)31(21)34-7)36(27-19-23(3)32(35-8)24(4)20-27)29-16-12-15-28(29)30(33(5)6)25-13-10-9-11-14-25;/h2*9-20,30H,1-8H3;/t2*30-;/m00./s1

SMILES string

[Fe].COc1c(C)cc(cc1C)P([C]2[CH][CH][CH][C]2[C@@H](N(C)C)c3ccccc3)c4cc(C)c(OC)c(C)c4.COc5c(C)cc(cc5C)P([C]6[CH][CH][CH][C]6[C@@H](N(C)C)c7ccccc7)c8cc(C)c(OC)c(C)c8

InChI key

HEJIDMKBSDYNOY-RELFUISISA-N

assay

≥97%

form

powder

optical purity

ee: ≥99%

General description

Mandyphos SL-M004-2 is a chiral ferrocenyl based diphosphine ligand belonging to the Mandyphos family.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

sold in collaboration with Solvias AG

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Modular chiral ligands: the profiling of the Mandyphos and Taniaphos ligand families.
Spindler F, et al.
Tetrahedron Asymmetry, 15(14), 2299-2306 (2004)

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