737488
Borane ethylenediamine complex
96%
Synonym(s):
Ethylenediaminebisborane
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About This Item
Empirical Formula (Hill Notation):
C2H14B2N2
CAS Number:
Molecular Weight:
87.77
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23
Assay
96%
form
solid
greener alternative product characteristics
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mp
114-130 °C (dec.)
greener alternative category
SMILES string
B.B.NCCN
InChI
1S/C2H8N2.2BH3/c3-1-2-4;;/h1-4H2;2*1H3
InChI key
MZYKPEFBHALNHU-UHFFFAOYSA-N
General description
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
Application
Enantioselective hydride attack of borane-ethylenediamine complex on inclusion compounds of ketones and certain diols and β-cyclodextrin may form optically active alcohols.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Asymmetric Induction by ?-Cyclodextrins in NaBH4 Reduction of Ketones.
Park KK, et al.
J. Incl. Phenom. Mol. Recog. Chem., 27(1), 41-48 (1997)
Ammonia-borane and related compounds as dihydrogen sources.
Anne Staubitz et al.
Chemical reviews, 110(7), 4079-4124 (2010-08-03)
Application
Rajasree, K. and Devaky, K. S.
Journal of Applied Polymer Science. Applied Polymer Symposium, 82, 593-593 (2001)
Structure
Ting, H. Y.; Watson, W. H.; Kelly, H. C.
Inorganic Chemistry, 11, 374-374 (1972)
Enantioselective Wittig-Horner reaction in the solid state.
Toda F and Akai H
The Journal of Organic Chemistry, 55(11), 3446-3447 (1990)
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