737488
Borane ethylenediamine complex
96%
Synonym(s):
Ethylenediaminebisborane
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About This Item
Empirical Formula (Hill Notation):
C2H14B2N2
CAS Number:
Molecular Weight:
87.77
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23
Assay:
96%
Form:
solid
SMILES string
B.B.NCCN
InChI
1S/C2H8N2.2BH3/c3-1-2-4;;/h1-4H2;2*1H3
InChI key
MZYKPEFBHALNHU-UHFFFAOYSA-N
assay
96%
form
solid
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114-130 °C (dec.)
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General description
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Application
Enantioselective hydride attack of borane-ethylenediamine complex on inclusion compounds of ketones and certain diols and β-cyclodextrin may form optically active alcohols.
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Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Asymmetric Induction by ?-Cyclodextrins in NaBH4 Reduction of Ketones.
Park KK, et al.
J. Incl. Phenom. Mol. Recog. Chem., 27(1), 41-48 (1997)
Ammonia-borane and related compounds as dihydrogen sources.
Anne Staubitz et al.
Chemical reviews, 110(7), 4079-4124 (2010-08-03)
Application
Rajasree, K. and Devaky, K. S.
Journal of Applied Polymer Science. Applied Polymer Symposium, 82, 593-593 (2001)
Structure
Ting, H. Y.; Watson, W. H.; Kelly, H. C.
Inorganic Chemistry, 11, 374-374 (1972)
Enantioselective Wittig-Horner reaction in the solid state.
Toda F and Akai H
The Journal of Organic Chemistry, 55(11), 3446-3447 (1990)
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