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Merck
CN

742368

Sigma-Aldrich

Di-μ-chlorobis[1-[(1R)-1-(dimethylamino)ethyl]-2-naphthyl-C,N]dipalladium(II)

≥97% (HPLC)

Synonym(s):

(R)-N,N-α-Trimethyl-1-naphthalenemethanamine palladium complex, Di-μ-chlorobis[1-[(1R)-1-(dimethylamino-κN)ethyl]-2-naphthalenyl-κC]dipalladium(II)

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About This Item

Empirical Formula (Hill Notation):
C28H32Cl2N2Pd2
CAS Number:
80145-77-3
Molecular Weight:
680.31
UNSPSC Code:
12352300
PubChem Substance ID:
329765568
NACRES:
NA.22

Key Documents

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Assay

≥97% (HPLC)

form

solid

optical activity

[α]/D -170±5°, c = 0.49 in dichloromethane

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

impurities

1 mol/mol dichlormethane

SMILES string

C[C@@H]1c2c(ccc3ccccc23)[Pd]4([Cl][Pd]5([Cl]4)c6ccc7ccccc7c6[C@@H](C)[N]5(C)C)[N]1(C)C

InChI

1S/2C14H16N.2ClH.2Pd/c2*1-11(15(2)3)13-10-6-8-12-7-4-5-9-14(12)13;;;;/h2*4-9,11H,1-3H3;2*1H;;/t2*11-;;;;/m11..../s1

InChI key

DSNXLWIMELRETE-KGFKVAEWSA-N

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
BCBG4198V
BCBG4198

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