742430
Benzyl azide solution
~0.5 M in dichloromethane, ≥95.0% (HPLC)
Synonym(s):
α-Azidotoluene solution, (Azidomethyl)benzene solution
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About This Item
Empirical Formula (Hill Notation):
C7H7N3
CAS Number:
Molecular Weight:
133.15
UNSPSC Code:
12352125
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
636825
Assay:
≥95.0% (HPLC)
Form:
solution
Quality Level
assay
≥95.0% (HPLC)
form
solution
concentration
~0.5 M in dichloromethane
impurities
≤2.0% water
storage temp.
2-8°C
SMILES string
[N-]=[N+]=NCc1ccccc1
InChI
1S/C7H7N3/c8-10-9-6-7-4-2-1-3-5-7/h1-5H,6H2
InChI key
UDLLFLQFQMACJB-UHFFFAOYSA-N
General description
Benzyl azide is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions.
Application
- Synthesis of Estrone Heterodimers and Evaluation of Their In Vitro Antiproliferative Activity.: This research investigates the synthesis of estrone heterodimers using benzyl azide as a key reagent, demonstrating significant antiproliferative activity, thus highlighting its potential in pharmaceutical intermediate synthesis (Bózsity N et al., 2024).
- Fluoride Abstraction Induced by Tris(pentafluoroethyl)difluorophosphorane: A Convenient Way to Synthesize Cationic N-Heterocyclic Carbene- and Cyclic (Alkyl)(amino)carbene-Ligated Copper Alkyne and Arene Complexes.: This paper describes a method for synthesizing copper alkyne and arene complexes using benzyl azide, emphasizing its role in innovative click chemistry applications (Riethmann M et al., 2024).
signalword
Warning
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
target_organs
Central nervous system
Storage Class
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
危险化学品
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Lachlan S Campbell-Verduyn et al.
Chemical communications (Cambridge, England), 16(16), 2139-2141 (2009-04-11)
Monodentate phosphoramidite ligands are used to accelerate the copper(i)-catalyzed 1,3-dipolar cycloaddition of azides and alkynes (CuAAC) rapidly yielding a wide variety of functionalized 1,4-disubstituted-1,2,3-triazoles; Cu(i) and Cu(ii) salts both function as the copper source in aqueous solution to provide excellent
Cu-catalyzed azide? alkyne cycloaddition
Meldal M & Torn?e CW
Chemical Reviews, 108(8), 2952-3015 (2008)
Tommy Siu-Ming Tang et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(30), 10729-10740 (2015-06-23)
The synthesis, characterization, photophysics, lipophilicity, and cellular properties of new phosphorescent ruthenium(II) polypyridine complexes functionalized with a dibenzocyclooctyne (DIBO) or amine moiety [Ru(N^N)2 (L)](PF6 )2 are reported (L=4-(13-N-(3,4:7,8-dibenzocyclooctyne-5-oxycarbonyl) amino-4,7,10-trioxa-tridecanyl-aminocarbonyl-oxy-methyl)-4'-methyl-2,2'-bipyridine bpy-DIBO, N^N=2,2'-bipyridine bpy (1 a), 1,10-phenanthroline phen (2 a); L=4-(13-amino-4,7,10-trioxa-tridecanylaminocarbonyl-oxy-methyl)-4'-methyl-2,2'-bipyridine bpy-NH2 , N^N=bpy
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 742430-10ML | 04061832886398 |
| 742430-50ML | 04061838136633 |