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Merck
CN

744255

Sigma-Aldrich

Sulfur dioxide

≥99.98%

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About This Item

Linear Formula:
SO2
CAS Number:
Molecular Weight:
64.06
Beilstein:
3535237
EC Number:
MDL number:
UNSPSC Code:
12142100
PubChem Substance ID:
NACRES:
NA.22
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vapor density

2.26 (21 °C, vs air)

Quality Level

vapor pressure

1779 mmHg ( 21 °C)

Assay

≥99.98%

form

gas

bp

−10 °C (lit.)

mp

−73 °C (lit.)

density

1.25 g/mL at 25 °C (lit.)

SMILES string

O=S=O

InChI

1S/O2S/c1-3-2

InChI key

RAHZWNYVWXNFOC-UHFFFAOYSA-N

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Application

Sulfur dioxide (SO2) can be used:
  • In the palladium catalyzed aminosulfonylation reaction.
  • To prepare 1,4-diazabicyclo[2.2.2]octane [DABCO. (SO2)2] or DABSO, which is used as a reagent to synthesize N-aminosulfonamides via aminosulfonylation process using palladium catalyst.
  • To synthesize polysulfobetaine (PSB/SO2) copolymer.

Packaging

500ml high pressure aluminum cylinder equipped with a stainless steel valve according to DIN 477-1.

Other Notes

For 744255-450G-EU packaging: 500 mL of aluminium cylinder equipped with brass valve.
For 744255-450G-EU: outlet fitting: DIN 477-1 no. 1, Z742160 or Z742161 are the recommended regulators.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation - Eye Dam. 1 - Press. Gas Liquefied gas - Skin Corr. 1B

Storage Class Code

2A - Gases

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

监管及禁止进口产品
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Synthesis and cyclopolymerization of diallylammoniomethanesulfonate
Ali, Shaikh A and Al-Hamouz OCS
Polym. Eng. Sci., 53(11), 2378-2388 (2013)
DABCO-bis (sulfur dioxide), DABSO, as a convenient source of sulfur dioxide for organic synthesis: utility in sulfonamide and sulfamide preparation.
Woolven H, et al.
Organic Letters, 13(18), 4876-4878 (2011)
Palladium-catalysed aminosulfonylation of aryl-, alkenyl-and heteroaryl halides: scope of the three-component synthesis of N-aminosulfonamides
Emmett EJ, et al.
Organic & Biomolecular Chemistry, 10(20), 4007-4014 (2012)
Philippe Bisseret et al.
Organic & biomolecular chemistry, 11(33), 5393-5398 (2013-07-16)
Although sulfur dioxide (SO2) has been used as a reagent for organic chemistry for more than one hundred years, being endowed with quite a distinct and varied reactivity profile, which allows the synthesis of a large range of compounds, its
Xin-Bao Wang et al.
Life sciences, 98(2), 63-67 (2014-01-15)
Sulfur dioxide (SO2) is a common air pollutant and is detrimental to many organs. Its toxic effects including oxidative damage, deoxyribonucleic acid (DNA) damage and inflammation have been extensively studied. However, recent studies showed that SO2 can be generated endogenously

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