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Merck
CN

744980

1-(Azidomethyl)-2-methylbenzene solution

~0.5 M in tert-butyl methyl ether, ≥97.0% (HPLC)

Synonym(s):

α-Azido-o-xylene solution, o-Methylbenzyl azide solution

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About This Item

Empirical Formula (Hill Notation):
C8H9N3
CAS Number:
Molecular Weight:
147.18
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4860454
Assay:
≥97.0% (HPLC)
Form:
liquid
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assay

≥97.0% (HPLC)

form

liquid

reaction suitability

reaction type: click chemistry

concentration

~0.5 M in tert-butyl methyl ether

impurities

≤2.0% water

storage temp.

2-8°C

SMILES string

Cc1ccccc1CN=[N+]=[N-]

InChI

1S/C8H9N3/c1-7-4-2-3-5-8(7)6-10-11-9/h2-5H,6H2,1H3

InChI key

TWZXVFYNRLIXRY-UHFFFAOYSA-N



pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-18.4 °F

flash_point_c

-28 °C

Regulatory Information

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Meina Liu et al.
Organic letters, 13(5), 1102-1105 (2011-02-12)
A structurally well-defined copper(I) isonitrile complex is shown to be an efficient, heterogeneous catalyst for the Huisgen azide-alkyne 1,3-dipolar cycloaddition under mild conditions in water. Notably, this catalyst can also be utilized in a three-component reaction of halides, sodium azide
Atif Sarwar et al.
PloS one, 10(4), e0123084-e0123084 (2015-05-01)
Recently, the attention of researchers has been drawn toward the synthesis of chitosan derivatives and their nanoparticles with enhanced antimicrobial activities. In this study, chitosan derivatives with different azides and alkyne groups were synthesized using click chemistry, and these were



Global Trade Item Number

SKUGTIN
744980-10ML04061838085375
744980-50ML04061838111616