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Sigma-Aldrich

C8-BTBT

≥99% (HPLC)

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Synonym(s):
2,7-Dioctyl[1]benzothieno[3,2-b][1]benzothiophene
Empirical Formula (Hill Notation):
C30H40S2
CAS Number:
Molecular Weight:
464.77
PubChem Substance ID:
NACRES:
NA.23

Assay

≥99% (HPLC)

form

powder

mp

108-112 °C

semiconductor properties

P-type (mobility=5.5 cm2/V·s)

SMILES string

CCCCCCCCC1=CC2=C(C=C1)C3=C(C(C=CC(CCCCCCCC)=C4)=C4S3)S2

InChI

1S/C30H40S2/c1-3-5-7-9-11-13-15-23-17-19-25-27(21-23)31-30-26-20-18-24(22-28(26)32-29(25)30)16-14-12-10-8-6-4-2/h17-22H,3-16H2,1-2H3

InChI key

YWIGIVGUASXDPK-UHFFFAOYSA-N

Related Categories

General description

C8-BTBT is a conducting polymer with [1]benzothieno[3,2-b][1]- benzothiophene (BTBT) as the base material for the development of air-stable semiconductors. It can form a spin coated thin film that can be used as a p-type semiconductor with charge mobility of 43 cm2V-1s-1. It exhibits highly ordered self-assembled monolayer (SAM) on graphene and hexagonal boron nitride (hBN) with sheet resistance: <1,000 ohm/sq

Application

C8-BTBT is a conjugating polymer that can be used in a variety of organic electronics based applications which includes organic photovoltaic cells (OPV), organic light emitting diodes (OLEDs) and organic thin film transistors (OTFTs).
High field-effect mobility of 5.5-5.7 cm2/Vs and high On/Off ratio of 109 ; solution-processed (solubility of 80 mg/mL) OFETs

Legal Information

Product of Nippon Kayaku

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Ultrahigh Vacuum Self-Assembly of Rotationally Commensurate C8-BTBT/MoS2/Graphene Mixed-Dimensional Heterostructures.
Liu X, et al.
Chemistry of Materials, 23(4), 523-526 (2019)
Darmawan; Peter;
Advances in Functional Materials, 22(21), 4577-4583 (2012)
Lu Lyu et al.
Physical chemistry chemical physics : PCCP, 19(2), 1669-1676 (2016-12-21)
Combining ultraviolet photoemission spectroscopy (UPS), X-ray photoemission spectroscopy (XPS), atomic force microscopy (AFM) and small angle X-ray diffraction (SAXD) measurements, we perform a systematic investigation on the correlations of the electronic structure, film growth and molecular orientation of 2,7-diocty[1]benzothieno[3,2-b]benzothiophene (C8-BTBT)
Xiuzhen Xu et al.
ACS nano, 13(5), 5910-5919 (2019-05-09)
High-performance phototransistors made from organic semiconductor single crystals (OSSCs) have attracted much attention due to the high responsivity and solution-processing capability of OSSCs. However, OSSC-based phototransistors capable of dual-band spectral response remain a difficult challenge to achieve because organic semiconductors
Ultra-high mobility transparent organic thin film transistors grown by an off-centre spin-coating method.
Yuan Y, et al.
Nature Communications, 5(4), 3005-3005 (2014)

Articles

Dr. Chan and researchers highlight flexible transistors are the building blocks of next-generation soft electronics. Small molecular weight organic semiconductors are among the most promising candidates for flexible transistor applications.

Intrinsically stretchable active layers for organic field-effect transistors (OFET) are discussed. Polymer structural modification & post-polymerization modifications are 2 methods to achieve this.

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