Skip to Content
Merck
CN

747777

[Ru(bpz)3][PF6]2

95%, powder

Synonym(s):

Tris(2,2′-bipyrazine)ruthenium bis(hexafluorophosphate), Tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Empirical Formula (Hill Notation):
C24H18F12N12P2Ru
CAS Number:
80907-56-8
Molecular Weight:
865.48
MDL number:
MFCD27952557
UNSPSC Code:
12161600
NACRES:
NA.22

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

[Ru(bpz)3][PF6]2, 95%

SMILES string

[N]12=CC=NC=C1C3=CN=CC=[N]3[Ru]24([N]5=CC=NC=C5C6=CN=CC=[N]64)([N]7=CC=NC=C78)[N]9=C8C=NC=C9

InChI

1S/3C8H6N4.Ru/c3*1-3-11-7(5-9-1)8-6-10-2-4-12-8;/h3*1-6H;

InChI key

VEEMVPAUPIJPLA-UHFFFAOYSA-N

assay

95%

form

powder

reaction suitability

core: ruthenium, reaction type: Photocatalysis, reagent type: catalyst

impurities

may contain ca. 5% acetonitrile

mp

162-210 °C (The MP data is a DECOMP) (lit.)

Quality Level

100

Related Categories

General description

[Ru(bpz)3][PF6]2 can be prepared from 2-iodopyrazine.

Application

[Ru(bpz)3][PF6]2 may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
SHBM4370
SHBG3066V

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Danielle M Schultz et al.
Beilstein journal of organic chemistry, 11, 61-65 (2015-02-12)
There has been a recent surge of interest in the use of transition metal polypyridyl complexes as visible light-absorbing photocatalysts for synthetic applications. Among the most attractive features of this approach is the availability of many known complexes with well-characterized
Knochel P and Molander GA
Comprehensive Organic Synthesis, 275-275 (2014)
Rodriguez J and Bonne D.
Stereoselective Multiple Bond-Forming Transformations in Organic Synthesis, 203-203 (2015)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service