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Merck
CN

747904

Boxed reaction: Heck Reaction in Lipshutz Surfactant

greener alternative
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About This Item

UNSPSC Code:
12161600

Key Documents

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reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

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Greener Alternative Product

greener alternative category

Aligned,

storage temp.

−20°C

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

This kit contains the reagents, catalyst, and solvent required to perform a Heck reaction in TPGS-750-M, a surfactant developed by the Lipshutz group as a greener alternative to organic solvents. This technology allows common metal-catalyzed reactions to be run under aqueous conditions, considerably reducing solvent waste. The components are pre-weighed in the appropriate amounts for a 1 mmol scale reaction.

Please refer to the attached Protocol for details.

Kit Components Also Available Separately

Product No.
Description
SDS
  • 676578Bis(tri-tert-butylphosphine)palladium(0) 10 mgSDS
  • 763918DL-α-Tocopherol methoxypolyethylene glycol succinate solution, 5 wt. % in H2O 2 mLSDS
  • T0886Triethylamine, ≥99% .42 mLSDS

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

5.0 °F - closed cup

flash_point_c

-15 °C - closed cup

Regulatory Information

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