749206
Poly(styrene-block-methyl methacrylate)
average Mn 82,000, block ratio of 2:1
Synonym(s):
PS-block-PMMA, PS-PMMA
InChI
1S/C8H8.C5H8O2/c1-2-8-6-4-3-5-7-8;1-4(2)5(6)7-3/h2-7H,1H2;1H2,2-3H3
InChI key
ADFPJHOAARPYLP-UHFFFAOYSA-N
form
solid
mol wt
average Mn 25,000 (PMMA), average Mn 57,000 (polystyrene), average Mn 82,000
transition temp
Tm 350-355 °C
Mw/Mn
<1.2
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General description
52 kDa PS; 52 kDa PMMA; m ~542; n ~250
PS Mn = 52 ± 5 kg/mol
PMMA Mn = 52 ± 5 kg/mol
PDI of the overall block copolymer <1.2
PS molecular weight verified by SEC (taking an aliquot from the reaction mixture) and the PMMA molecular weight by NMR spectroscopy. The overall block copolymer molecular weight distribution would be determined by SEC.
PS Mn = 52 ± 5 kg/mol
PMMA Mn = 52 ± 5 kg/mol
PDI of the overall block copolymer <1.2
PS molecular weight verified by SEC (taking an aliquot from the reaction mixture) and the PMMA molecular weight by NMR spectroscopy. The overall block copolymer molecular weight distribution would be determined by SEC.
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Novel fabrication of 2D and 3D inverted opals and their application.
Jae Ah Lee et al.
Small (Weinheim an der Bergstrasse, Germany), 7(18), 2581-2586 (2011-08-03)
F N K Kwong et al.
The Journal of bone and joint surgery. British volume, 88(1), 120-122 (2005-12-21)
The outcome of a cemented hip arthroplasty is partly dependent on the type of cement which is used. The production of an interface gap between the stem and the cement mantle as a result of shrinkage of the cement, may
M H Geiger et al.
Clinical orthopaedics and related research, (382)(382), 258-266 (2001-01-12)
This controlled study compared the strength and porosity of 48 polymethylmethacrylate cement-implant constructs prepared with open bowl versus vacuum mix technique. Forty-eight blast finished stainless steel rods of 13 mm diameter were implanted with centralizers into 17-mm inner diameter tubes
S J Breusch et al.
Acta orthopaedica Scandinavica, 72(1), 29-35 (2001-05-01)
In a cadaver study, we prepared 29 paired human cadaver femora using 3 different broaches of identical geometry but different surface characteristics. In one group of 20 pairs, preparation with chipped-toothed broaches was compared to diamond-shaped broaches; in the other
Takeshi Ueki et al.
The journal of physical chemistry. B, 111(18), 4750-4754 (2007-02-27)
The solubility and phase behavior of poly(benzyl methacrylate) (PBzMA) and poly(styrene-co-methyl methacrylate) (P(St-co-MMA)) in a hydrophobic ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethane sulfone)imide ([C(2)mim][NTf(2)]), have been explored as a function of temperature. Although both polymers have solvatophobic phenyl groups and solvatophilic methacrylate
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