750719
Potassium isoquinoline-6-trifluoroborate
97%
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About This Item
Empirical Formula (Hill Notation):
C9H6BF3KN
Molecular Weight:
235.06
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C9H6BF3N.K/c11-10(12,13)9-2-1-8-6-14-4-3-7(8)5-9;/h1-6H;/q-1;+1
SMILES string
[K+].F[B-](F)(F)c1ccc2cnccc2c1
InChI key
YHMRPEZLHYKXIX-UHFFFAOYSA-N
assay
97%
form
solid
mp
362-369 °C
storage temp.
2-8°C
Application
Product may contain some levels of internal salt due to free nitrogen, however should still be utilizable for Suzuki-Miyuara couplings.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Gary A Molander et al.
Organic letters, 13(5), 1242-1245 (2011-02-08)
A large array of aryl and heteroaryl mesylates have been successfully employed as electrophiles in a Csp(2)-Csp(3) Suzuki-Miyaura cross-coupling with potassium ammonio- and amidomethyltrifluoroborates to afford the corresponding products in high yields.
Jessica Raushel et al.
The Journal of organic chemistry, 76(8), 2762-2769 (2011-03-17)
A reinvestigation into the chemical composition of potassium aminomethyltrifluoroborates is reported. These trifluoroborato salts have been reassigned as zwitterionic ammoniomethyltrifluoroborates. Minor adjustments to the previously disclosed reaction conditions are reported that permit a similar level of activity as nucleophiles in
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