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Merck
CN

753955

ICBA

99% (HPLC)

Synonym(s):

1′,1′′,4′,4′′-Tetrahydro-di[1,4]methanonaphthaleno[1,2:2′,3′,56,60:2′′,3′′][5,6]fullerene-C60, C60 derivative, indene-C60 bisadduct

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About This Item

Empirical Formula (Hill Notation):
C78H16
CAS Number:
Molecular Weight:
952.96
MDL number:
NACRES:
NA.23
UNSPSC Code:
12352103
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Quality Level

assay

99% (HPLC)

form

solid

loss

0.5 wt. % TGA, 235 °C

mp

253-260 °C

orbital energy

LUMO 3.67 eV (CV)

OPV device performance

ITO/PEDOT:PSS/P3HT: ICBA (1:1)/Al

  • Short-circuit current density (Jsc): 10.82 mA/cm2
  • Open-circuit voltage (Voc): 0.78 V
  • Fill Factor (FF): 0.56
  • Power Conversion Efficiency (PCE): 4.65 %
, ITO/PEDOT:PSS/P3HT:ICBA(1.5:1)/LiF/Al
  • Short-circuit current density (Jsc): 10.53 mA/cm2
  • Open-circuit voltage (Voc): 0.83 V
  • Fill Factor (FF): 0.60
  • Power Conversion Efficiency (PCE): 5.26 %

General description

The performance of indene-C60 bisadduct (ICBA) as organic solar cell (OSC) has been described in a study. Simple preparation and high solubility inorganic solvents renders ICBA as an efficient substitute to [6,6]-phenyl-C61 butyric acid methyl ester (PCBM).
ICBA is a C60 derivative that can be synthesized from C60 and indene. It is an acceptor material with shallow lowest occupied molecular orbital(LUMO) which can be used to enhance the performance of polymeric solar cells(PSCs).

Application

A ternary bulk heterojunction system (BHJ) may be fabricated with ICBA low band gap polymer, for IR sensitized organic solar cells. 1-3ICBA/thiazolo-thiazolo donor polymer blend may be used to enhance the charge generation in BHJ solar cells.
ICBA can be used with poly(3-hexylthiophene)(P3HT) as an active layer which can be used in the fabrication of organic solar cells(OSCs).ICBA in combination with thiazolo-thiazolo can be used as a donor. It can be blended with PCBM for photovoltaic based application.


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Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Articles

Progress in solution-processed functional materials leads to thin-film optoelectronic devices for industrial and consumer electronics.

SWCNTs show promise in FETs, solar cells, and photodetectors due to their ultrafast charge transport mobility.

Solution-processed organic photovoltaic devices (OPVs) have emerged as a promising clean energy generating technology due to their ease of fabrication, potential to enable low-cost manufacturing via printing or coating techniques, and ability to be incorporated onto light weight, flexible substrates.

View All Articles

Photo-physics of PTB7, PCBM and ICBA based ternary solar cells.
Sharma R, et al.
Organic Electronics, 34(4), 111-117 (2016)
Optimization of the structural configuration of ICBA/P3HT photovoltaic cells.
Nemnes GA, et al.
Applied Surface Science, 424(4), 264-268 (2017)
Temperature dependence of P3HT: ICBA polymer solar cells.
2017 International Conference on Numerical Simulation of Optoelectronic Devices, 133-134 (2017)



Global Trade Item Number

SKUGTIN
753955-250MG04061832988160