754943
Molybdenumhexacarbonyl
packaged for use in deposition systems
Synonym(s):
Hexacarbonylmolybdenum(0)
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About This Item
Linear Formula:
Mo(CO)6
CAS Number:
Molecular Weight:
264.00
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
237-713-3
MDL number:
vapor density
9.1 (vs air)
Quality Level
assay
99.9% (trace metals analysis)
form
solid
reaction suitability
core: molybdenum
bp
156 °C (lit.)
mp
150 °C (dec.) (lit.)
density
1.96 g/mL at 25 °C (lit.)
SMILES string
[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/6CO.Mo/c6*1-2;
InChI key
KMKBZNSIJQWHJA-UHFFFAOYSA-N
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation
Storage Class
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Patrik Nordeman et al.
The Journal of organic chemistry, 77(24), 11393-11398 (2012-12-05)
A bridged two-vial system aminocarbonylation protocol where Mo(CO)(6) functions as an external in situ solid source of CO has been developed. For the first time both nitro group containing aryl/heteroaryl iodides and bromides gave good to excellent yields in the
John Spencer
Future medicinal chemistry, 2(2), 161-168 (2011-03-24)
Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, tolerating unsaturation, steric hindrance and
Qingxi Meng et al.
Journal of molecular modeling, 18(8), 3489-3499 (2012-02-03)
Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) for Mo]. In the Mo-catalyzed intramolecular Pauson-Khand reaction, the C–C oxidative
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 754943-25G | 04061833491041 |