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755508

8-Methylquinoline N-oxide

Name: 8-Methylquinoline <I>N</I>-oxide
Brand: ALDRICH

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₉NO

CAS Number:

4053-38-7

Molecular Weight:

159.18

NACRES:

NA.22

PubChem Substance ID:

329766511

UNSPSC Code:

12352005

MDL number:

MFCD22666433

Form:

solid

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Properties

form

solid

Quality Level

100

mp

240-260 °C

storage temp.

2-8°C

SMILES string

[O-][N+]1=CC=CC2=C1C(C)=CC=C2

InChI

1S/C10H9NO/c1-8-4-2-5-9-6-3-7-11(12)10(8)9/h2-7H,1H3

InChI key

PIOGDSHYODXWAK-UHFFFAOYSA-N

Description

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Gold-catalyzed highly regioselective oxidation of C-C triple bonds without acid additives: propargyl moieties as masked α,β-unsaturated carbonyls.

Biao Lu et al.

Journal of the American Chemical Society, 132(40), 14070-14072 (2010-09-22)

Gold-catalyzed intermolecular oxidations of internal alkynes have been achieved with high regioselectivities using 8-alkylquinoline N-oxides as oxidants and in the absence of acid additives. Synthetically versatile α,β-unsaturated carbonyls are obtained in good to excellent yields and with excellent E-selectivities. A

Global Trade Item Number

SKU	GTIN
755508-1G	04061832908809
755508-5G	04061833555774