755591
(Acetonitrile)(2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl)gold(I) hexafluoroantimonate
Synonym(s):
SPhos Au(MeCN)SbF6
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About This Item
InChI
1S/C26H35O2P.C2H3N.Au.6FH.Sb/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;1-2-3;;;;;;;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6
SMILES string
[Au+].CC#N.F[Sb-](F)(F)(F)(F)F.COc1cccc(OC)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4
InChI key
DNWMYIZXJFLNDN-UHFFFAOYSA-H
form
solid
reaction suitability
core: gold, reagent type: catalyst
impurities
5-10% SPhos-Oxide
mp
>300 °C
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2
Storage Class
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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The research of the Echavarren group centers on the development of new reactions based on the use of electrophilic complexes of Au(I), Pt(II), and other transition metals as catalysts and their applications in organic synthesis of complex, biologically active molecules. The Echavarren group is also examining new strategies for the synthesis of polyarenes of interest in material science. In particular, they are interested in the ready construction of C-60 skeletons using reactions catalyzed by Pd(0) and other transition metals.
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