755591
(Acetonitrile)(2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl)gold(I) hexafluoroantimonate
Synonym(s):
SPhos Au(MeCN)SbF6
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About This Item
form
solid
reaction suitability
core: gold
reagent type: catalyst
impurities
5-10% SPhos-Oxide
mp
>300 °C
SMILES string
[Au+].CC#N.F[Sb-](F)(F)(F)(F)F.COc1cccc(OC)c1-c2ccccc2P(C3CCCCC3)C4CCCCC4
InChI
1S/C26H35O2P.C2H3N.Au.6FH.Sb/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;1-2-3;;;;;;;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6
InChI key
DNWMYIZXJFLNDN-UHFFFAOYSA-H
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2
Storage Class Code
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Regulatory Information
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The research of the Echavarren group centers on the development of new reactions based on the use of electrophilic complexes of Au(I), Pt(II), and other transition metals as catalysts and their applications in organic synthesis of complex, biologically active molecules. The Echavarren group is also examining new strategies for the synthesis of polyarenes of interest in material science. In particular, they are interested in the ready construction of C-60 skeletons using reactions catalyzed by Pd(0) and other transition metals.
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