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Merck
CN

757144

Vinylene carbonate

greener alternative

contains 80 ppm BHT as stabilizer, 99%

Synonym(s):

1,3-Dioxol-2-one, VC

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About This Item

Empirical Formula (Hill Notation):
C3H2O3
CAS Number:
872-36-6
Molecular Weight:
86.05
UNSPSC Code:
26111700
NACRES:
NA.23
PubChem Substance ID:
329766650
EC Number:
212-825-5
Beilstein/REAXYS Number:
105683
MDL number:
MFCD00005380

Key Documents

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SMILES string

O=C1OC=CO1

InChI key

VAYTZRYEBVHVLE-UHFFFAOYSA-N

InChI

1S/C3H2O3/c4-3-5-1-2-6-3/h1-2H

assay

99%

form

liquid

contains

80 ppm BHT as stabilizer

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

refractive index

n20/D 1.421 (lit.), n20/D 1.422

bp

162 °C (lit.)

mp

19-22 °C (lit.)

application(s)

battery manufacturing

greener alternative category

, Enabling

storage temp.

2-8°C

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Vinylene carbonate (VC) can be used as an electrolytic additive for ionic liquid electrolyte for the formation of lithium-ion batteries. It can also be used in the formation of hybrid solid electrolyte interphase (SEI) for the fabrication of lithium-based batteries.

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Oral

target_organs

Liver,Stomach

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

181.9 °F - closed cup

flash_point_c

83.3 °C - closed cup

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBQ7836V
MKBK7063

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Electrochemical investigations of ionic liquids with vinylene carbonate for applications in rechargeable lithium ion batteries
Sun X and Dai S
Electrochimica Acta, 55(15), 4618-4626 (2010)
Vinylene carbonate-LiNO3: a hybrid additive in carbonic ester electrolytes for SEI modification on Li metal anode
Guo J, et al.
Electrochemical Communications, 51(15), 59-63 (2015)
Surface analytical study regarding the solid electrolyte interphase composition of nanoparticulate SnO2 anodes for Li-ion batteries
Winkler V, et al.
The Journal of Physical Chemistry C, 120(43), 24706-24714 (2016)
Matthieu Groh et al.
European journal of internal medicine, 26(7), 545-553 (2015-05-15)
To develop disease-specific recommendations for the diagnosis and management of eosinophilic granulomatosis with polyangiitis (Churg-Strauss syndrome) (EGPA). The EGPA Consensus Task Force experts comprised 8 pulmonologists, 6 internists, 4 rheumatologists, 3 nephrologists, 1 pathologist and 1 allergist from 5 European
Stefan Hilf et al.
Journal of the American Chemical Society, 130(33), 11040-11048 (2008-07-24)
The selective placement of a functional group at the chain end of a ring-opening metathesis polymer using ruthenium carbene initiators has been a significant limitation. Here we demonstrate a highly effective and facile end-capping technique for ROMP with living ruthenium
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