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Merck
CN

760455

Ethyl 2-(phenylcarbonothioylthio)propionate

97% (HPLC)

Synonym(s):

2-[(Phenylthioxomethyl)thio]propanoic acid ethyl ester, Ethyl 2-(phenylcarbonothioylthio)propanoate

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About This Item

Empirical Formula (Hill Notation):
C12H14O2S2
CAS Number:
412015-83-9
Molecular Weight:
254.37
NACRES:
NA.23
PubChem Substance ID:
329766866
UNSPSC Code:
12352100
MDL number:
MFCD22200547

Key Documents

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InChI

1S/C12H14O2S2/c1-3-14-11(13)9(2)16-12(15)10-7-5-4-6-8-10/h4-9H,3H2,1-2H3

SMILES string

CCOC(=O)C(C)SC(=S)c1ccccc1

InChI key

NXWVPIWRMPQYEX-UHFFFAOYSA-N

assay

97% (HPLC)

form

liquid

refractive index

n20/D 1.611

density

1.163 g/mL at 25 °C

storage temp.

2-8°C

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

RAFT agent for controlled radical polymerization; especially suited for methacrylates and methacrylamides; Chain Transfer Agent (CTA)
Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization

Storage Class

12 - Non Combustible Liquids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBK2436V
MKBK2436

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Micro Review of RAFT Polymerization

Micro review of reversible addition/fragmentation chain transfer (RAFT) polymerization.

Protocols

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

Polymerizing via ATRP

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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