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760838

Allyl tetraisopropylphosphorodiamidite

95%

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About This Item

Linear Formula:
[[(CH3)2CH]2N]2POCH2CH=CH2
CAS Number:
108554-72-9
Molecular Weight:
288.41
NACRES:
NA.22
PubChem Substance ID:
329766898
UNSPSC Code:
12352302
MDL number:
MFCD00191714
Assay:
95%
Form:
liquid
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assay

95%

form

liquid

refractive index

n20/D 1.466 (lit.), n20/D 1.467

bp

114-117 °C/0.4 mmHg (lit.)

density

0.903 g/mL at 25 °C (lit.), 0.910 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)N(C(C)C)P(OCC=C)N(C(C)C)C(C)C

InChI

1S/C15H33N2OP/c1-10-11-18-19(16(12(2)3)13(4)5)17(14(6)7)15(8)9/h10,12-15H,1,11H2,2-9H3

InChI key

ZTEGHJIXOZLSOH-UHFFFAOYSA-N

Application

Allyl tetraisopropylphosphorodiamidite may be used in the total synthesis of (−)-tetrahydrolipstatin, dolabelide C, (-)-salicylihalamides A and B.
Phosphitylation agent used in the preparation of oligonucleotides. Selective deallylation is accomplished by palladium catalysis.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Codes

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class

10 - Combustible liquids

WGK

WGK 3

Flash Point (°F)

188.0 °F

Flash Point (°C)

86.67 °C

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