761702
4-Trifluoromethyl-1-phenylvinylboronic acid pinacol ester
97%
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About This Item
Empirical Formula (Hill Notation):
C15H18BF3O2
Molecular Weight:
298.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C15H18BF3O2/c1-10(16-20-13(2,3)14(4,5)21-16)11-6-8-12(9-7-11)15(17,18)19/h6-9H,1H2,2-5H3
SMILES string
CC1(C)OB(OC1(C)C)C(=C)c2ccc(cc2)C(F)(F)F
InChI key
NGEPDYSRKLLXMJ-UHFFFAOYSA-N
assay
97%
form
solid
mp
47-53 °C
storage temp.
2-8°C
Application
Common reaction partner for palladium-catalyzed carbon-carbon cross coupling formation (Suzuki Reaction).
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Hwanjong Jang et al.
Journal of the American Chemical Society, 133(20), 7859-7871 (2011-04-30)
Cu-catalyzed methods for site-selective hydroboration of terminal alkynes, where the internal or α-vinylboronate is generated predominantly (up to >98%) are presented. Reactions are catalyzed by 1-5 mol % of N-heterocyclic carbene (NHC) complexes of copper, easily prepared from N-aryl-substituted commercially
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