762334
Diethyl methylphosphonite
97%, liquid
Synonym(s):
Diethoxymethylphosphine
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About This Item
Empirical Formula (Hill Notation):
C5H13O2P
CAS Number:
Molecular Weight:
136.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
EC Number:
239-805-9
MDL number:
Product Name
Diethyl methylphosphonite, 97%
Quality Segment
assay
97%
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index
n20/D 1.419
density
0.907 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
CCOP(C)OCC
InChI
1S/C5H13O2P/c1-4-6-8(3)7-5-2/h4-5H2,1-3H3
InChI key
NSSMTQDEWVTEKN-UHFFFAOYSA-N
Application
Diethyl methylphosphonite can be used as a mild reducing reagent in the oxalimide cyclization of oxalylazetidinonyl thiocarbonates and thioesters. It can also be used in the synthesis of β-carboxamido-phosphon(in)ic acids as potential inhibitors of human mast cell chymase.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 3
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
84.9 °F
flash_point_c
29.4 °C
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