762393
2-(4,4-Dimethyl-4,5-dihydro-2-oxazolyl)pyridine
97%
Synonym(s):
4,4-Dimethyl-2-(pyridin-2-yl)-4,5-dihydrooxazole, pymox-Me2
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About This Item
Empirical Formula (Hill Notation):
C10H12N2O
CAS Number:
Molecular Weight:
176.22
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
form
liquid
reaction suitability
reagent type: ligand
refractive index
n20/D 1.533
density
1.050 at 25 °C
storage temp.
2-8°C
SMILES string
CC1(C)COC(=N1)c2ccccn2
InChI
1S/C10H12N2O/c1-10(2)7-13-9(12-10)8-5-3-4-6-11-8/h3-6H,7H2,1-2H3
InChI key
ZANPCQHDEUORJP-UHFFFAOYSA-N
Application
Ligand for Ruthenium catalyzed C-H bond oxidation of arylalkanes.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Chae S Yi et al.
Organic letters, 11(7), 1567-1569 (2009-02-28)
The cationic complex [(pymox-Me(2))RuCl(2)](+)BF(4)(-) was found to be a highly effective catalyst for the C-H bond oxidation reaction of arylalkanes in water. For example, the treatment of ethylbenzene (1.0 mmol) with t-BuOOH (3.0 mmol) and 1.0 mol % of the
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