762415
2-Azido-1,3-dimethylimidazolinium hexafluorophosphate
97%
Synonym(s):
2-Azido-4,5-dihydro-1,3-dimethyl-1H-imidazolium hexafluorophosphate
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About This Item
Empirical Formula (Hill Notation):
C5H10F6N5P
CAS Number:
Molecular Weight:
285.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352202
MDL number:
Assay:
97%
Form:
solid
Quality Level
assay
97%
form
solid
reaction suitability
reaction type: click chemistry
availability
available only in USA
mp
205-210 °C
storage temp.
−20°C
SMILES string
F[P-](F)(F)(F)(F)F.CN1CC[N+](C)=C1N=[N+]=[N-]
InChI
1S/C5H10N5.F6P/c1-9-3-4-10(2)5(9)7-8-6;1-7(2,3,4,5)6/h3-4H2,1-2H3;/q+1;-1
InChI key
SKAIRSILDPLHCV-UHFFFAOYSA-N
Application
Efficient diazo transfer reagent for the preparation of azides from primary amines. An alternative to tosyl azide with an easier-to-separate water soluble by-product.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Self-react. C
Storage Class
5.2 - Organic peroxides and self-reacting hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Direct Synthesis of Organic Azides from Primary Amines with 2-Azido-1,3-dimethylimidazolinium Hexafluorophosphate.
Kitamura, M.
European Journal of Organic Chemistry, 458-462 (2011)
Mitsuru Kitamura, et al
Synthesis, 7, 1037-1044 (2011)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 762415-25G | 04061833510735 |
| 762415-1G | 04061841714965 |
| 762415-5G | 04061833332153 |