762911
S-(4-Azidobutyl)thioacetate
97%
Synonym(s):
S-(4-Azidobutyl) ethanethioate
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About This Item
Empirical Formula (Hill Notation):
C6H11N3OS
CAS Number:
Molecular Weight:
173.24
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI key
IFUADVSNNZKOGP-UHFFFAOYSA-N
SMILES string
CC(=O)SCCCCN=[N+]=[N-]
InChI
1S/C6H11N3OS/c1-6(10)11-5-3-2-4-8-9-7/h2-5H2,1H3
assay
97%
form
liquid
refractive index
n20/D 1.501
density
1.100 g/mL at 25 °C
General description
S-(4-Azidobutyl)thioacetate is used as a precursor in the formation of organic self-assembled monolayers (SAMs) on metals. They are chemisorbed onto metal surfaces to form self-assembled monolayers with a high degree of structural order. They are often used as a molecular template to form functional nanostructures.
Application
Used in the formation of Self-Assembled Monolayers on gold electrodes to modify its work function.
Features and Benefits
High chemical stability in air or solution. Prevents undesirable oxidation of thiol groups in oxygen containing atmosphere. Forms homogeneous interface structure in SAMs.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
>230.0 °F
flash_point_c
> 110 °C
Regulatory Information
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The Thioacetate-Functionalized Self-Assembled Monolayers on Au: Toward High-Performance Ion-Selective Electrode for Ag
Jin, J., Zhou, W. J., Chen, Y., Liu, Y. L., Sun, X. Q., & Xi, H. T.
Bull. Korean Chem. Soc., 35(2), 601-601 (2014)
Formation and Structure of Self-Assembled Monolayers of Octylthioacetates on Au (111) in Catalytic Tetrabutylammonium Cyanide Solution
Park, T., Kang, H., Choi, I., Chung, H., Ito, E., Hara, M., & Noh, J.
Bull. Korean Chem. Soc., 30(2), 441-441 (2009)
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