Skip to Content
Merck
CN

763101

Sigma-Aldrich

(Acetonitrile)[(2-di-tert-butylphosphino-3,4,5,6-tetramethyl)-2′,4′,6′-triisopropylbiphenyl]gold(I) hexafluoroantimonate

Synonym(s):

Me4-tert-butyl XPhos-AuMeCN SbF6

Sign Into View Organizational & Contract Pricing

Select a Size

About This Item

Empirical Formula (Hill Notation):
C35H56AuF6NPSb
CAS Number:
1334547-72-6
Molecular Weight:
954.52
MDL number:
MFCD22417229
UNSPSC Code:
12352300
PubChem Substance ID:
329767029

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

form

solid

reaction suitability

core: gold
reagent type: catalyst

impurities

<5% Chloroform

mp

200-217 °C (decomposition)

SMILES string

CC#[N+][Au].F[Sb-](F)(F)(F)(F)F.CC(C)c1cc(C(C)C)c(c(c1)C(C)C)-c2c(C)c(C)c(C)c(C)c2P(C(C)(C)C)C(C)(C)C

InChI

1S/C33H53P.C2H3N.Au.6FH.Sb/c1-19(2)26-17-27(20(3)4)30(28(18-26)21(5)6)29-24(9)22(7)23(8)25(10)31(29)34(32(11,12)13)33(14,15)16;1-2-3;;;;;;;;/h17-21H,1-16H3;1H3;;6*1H;/q;;+1;;;;;;;+5/p-6

InChI key

RYAHVCSWEWNLIW-UHFFFAOYSA-H

Application

Effective gold catalyst for selective 6-endo dig carbocyclizations.

Pictograms

Health hazard
GHS08

Signal Word

Warning

Hazard Statements

H351,H361d,H373

Precautionary Statements

P201 - P308 + P313

Hazard Classifications

Carc. 2 - Repr. 2 - STOT RE 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

新产品
This item has

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
SHBC3650

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Francis Barabé et al.
Organic letters, 13(20), 5580-5583 (2011-09-16)
A gold-catalyzed synthesis of fused carbocycles via a regioselective 6-endo dig process is reported. The selectivity can be modulated by the steric and electronic properties of gold(I) complexes. The ligands can influence the pathway selectivity for the first bond formation

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service