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Merck
CN

763179

Sigma-Aldrich

{2-[(α-Methyl)diphenylphosphinomethyl]ferrocenyl}palladium(II) acetate

Synonym(s):

{2-[1-(Diphenylphosphino)ethyl]ferrocenyl}palladium(II) acetate

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About This Item

Empirical Formula (Hill Notation):
C26H25FeO2PPd
CAS Number:
925217-70-5
Molecular Weight:
562.71
MDL number:
MFCD22417232
UNSPSC Code:
12352300
PubChem Substance ID:
329767034

Key Documents

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form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

145-185 °C (decomposition)

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.CC([C]2[CH][CH][CH][C]2[Pd]OC(C)=O)P(c3ccccc3)c4ccccc4

InChI

1S/C19H17P.C5H5.C2H4O2.Fe.Pd/c1-16(17-10-8-9-11-17)20(18-12-4-2-5-13-18)19-14-6-3-7-15-19;1-2-4-5-3-1;1-2(3)4;;/h2-10,12-16H,1H3;1-5H;1H3,(H,3,4);;/q;;;;+1/p-1

InChI key

GIYKFWJEBAVHNF-UHFFFAOYSA-M

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Warning

Hazard Statements

H315,H351,H361d

Hazard Classifications

Carc. 2 - Repr. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBC3108

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Ping He et al.
Organic letters, 9(2), 343-346 (2007-01-16)
Anionic four-electron donor-based palladacycle-catalyzed 1,4-additions of arylboronic acids with alpha,beta-unsaturated ketones and 1,2-additions of arylboronic acids with aldehydes and alpha-ketoesters are described. Our study demonstrated that palladacycles were highly efficient, practical catalysts for these addition reactions. The work described here

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