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763276

Bis(N,N-dimethyl-β-alaninato)palladium(II)

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About This Item

Empirical Formula (Hill Notation):
C10H20N2O4Pd
CAS Number:
934215-85-7
Molecular Weight:
338.70
PubChem Substance ID:
329767040
UNSPSC Code:
12352300
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assay

97%

form

solid

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

152-172 °C

storage temp.

2-8°C

SMILES string

CN(C)CCC(=O)O[Pd]OC(=O)CCN(C)C

InChI

1S/2C5H11NO2.Pd/c2*1-6(2)4-3-5(7)8;/h2*3-4H2,1-2H3,(H,7,8);/q;;+2/p-2

InChI key

ZXNOSELUGCGIPS-UHFFFAOYSA-L

Application

Phosphine free palladium catalyst for Suzuki Cross-Couplings

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
SHBC5270

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Xin Cui et al.
The Journal of organic chemistry, 72(24), 9342-9345 (2007-11-02)
N,O-Bidentate compounds were systematically evaluated as phosphine-free ligands for Pd-catalyzed C-C bond-formation reactions through kinetic measurements. Pd(quinoline-8-carboxylate)2 was identified as one of the most efficient, yet still low-priced, phosphine-free catalysts for Heck as well as Suzuki reactions of unactivated aryl
Cui, X.; et al.
Synthesis, 3, 393-393 (2007)

Global Trade Item Number

SKUGTIN
763276-1G04061826252062
763276-250MG04061832970868