763284
9-Azabicyclo[3.3.1]nonane N-oxyl
95%, solid
Greener Alternative
Synonym(s):
9-Azabicyclo[3.3.1]nonane N-oxyl radical, ABNO
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About This Item
Empirical Formula (Hill Notation):
C8H14NO
CAS Number:
Molecular Weight:
140.20
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Beilstein/REAXYS Number:
1681761
Product Name
9-Azabicyclo[3.3.1]nonane N-oxyl, 95%
Quality Segment
assay
95%
form
solid
reaction suitability
reagent type: ligand
greener alternative product characteristics
Catalysis
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Greener Alternative Product
mp
65-70 °C
greener alternative category
, Aligned
storage temp.
2-8°C
SMILES string
C[C@@]12CCC[C@@](C)(CCC1)N2[O]
InChI
1S/C10H18NO/c1-9-5-3-7-10(2,11(9)12)8-4-6-9/h3-8H2,1-2H3/t9-,10+
InChI key
GGWCZKZSILYISB-AOOOYVTPSA-N
General description
9-Azabicyclo[3.3.1]nonane N-oxyl (ABNO) belongs to a sterically unhindered and stable class of nitroxyl radicals. It efficiently catalyzes the oxidation of alcohols to afford the corresponding carbonyl compounds. ABNO along with (MeObpy)CuI(OTf) (MeObpy =4,4′-dimethoxy-2,2′-bipyridine) comprises a catalytic system. This catalytic system is useful for the aerobic oxidation of all categories of alcohols.
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Application
9-Azabicyclo[3.3.1]nonane N-oxyl (ABNO) may be employed for the aerobic oxidation of alcohols.
Catalytic oxidant for copper-catalyzed greener oxidation of alcohols under aerobic conditions.
Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems
Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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