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Merck
CN

763500

Cyanomethyl benzodithioate

98% (HPLC)

Synonym(s):

Cyanomethyl dithiobenzoate

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About This Item

Empirical Formula (Hill Notation):
C9H7NS2
CAS Number:
28740-46-7
Molecular Weight:
193.29
NACRES:
NA.23
PubChem Substance ID:
329767058
UNSPSC Code:
12352100
MDL number:
MFCD22666444

Key Documents

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Product Name

Cyanomethyl benzodithioate, 98% (HPLC)

InChI

1S/C9H7NS2/c10-6-7-12-9(11)8-4-2-1-3-5-8/h1-5H,7H2

SMILES string

S=C(SCC#N)C1=CC=CC=C1

InChI key

SBFVXSRJTJHHPR-UHFFFAOYSA-N

assay

98% (HPLC)

form

solid

mp

42-47 °C

storage temp.

2-8°C

Application

RAFT agent for controlled radical polymerization, especially suited for the polymerization of methacrylates/methacrylamides, and to a lesser extent acrylates/acrylamides and styrenes. Chain Transfer Agent (CTA)

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBL2427

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Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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