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Merck
CN

764175

P(Cy3) Pd G3

97%, solid

Synonym(s):

Palladium G3-Tricyclohexylphosphine, [(Tricyclohexylphosphine)-2-(2′-aminobiphenyl)]palladium(II) methanesulfonate

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About This Item

Empirical Formula (Hill Notation):
C31H46NO3PPdS
CAS Number:
Molecular Weight:
650.16
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
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Product Name

P(Cy3) Pd G3, 97%

Quality Level

product line

Buchwald precatalyst Generation 3

assay

97%

form

solid

feature

generation 3

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

mp

219-224 °C (decomposition)

functional group

phosphine

SMILES string

CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.C3CCC(CC3)P(C4CCCCC4)C5CCCCC5

InChI

1S/C18H33P.C12H10N.CH4O3S.Pd/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h16-18H,1-15H2;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1

InChI key

HZVUEHVNPWCEIW-UHFFFAOYSA-M

General description

P(Cy3) Pd G3 is a 3rd generation phosphine functionalized palladium precatalyst used in organic synthesize, that is often used in cross-coupling reactions.


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Articles

G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.

Tools aid in kit setup for organic chemistry techniques, ensuring ease and success.

All of the preformed catalysts used in the kit are air and moisture stable complexes in their commercially available form.

View All Articles

Catalyst-Controlled 1, 2-and 1, 1-Arylboration of ?-Alkyl Alkenyl Arenes
Bergmann AM, et al.
Angewandte Chemie (International Edition in English), 131(6), 1733-1737 (2019)
Synthesis of gem-Difluorinated 1, 3-Dienes via Synergistic Cu/Pd-Catalyzed Borodifluorovinylation of Alkynes
Xu WY, et al.
Organic Letters, 24(32), 5884-5889 (2022)



Global Trade Item Number

SKUGTIN
764175-1G04061826654521
764175-250MG04061833230909
764175-5G04061833340363