766216
2-[(4S)-4,5-Dihydro-4-(1-methylethyl)-2-oxazolyl]-N-{2-[(4S)-4-(1,1-dimethylethyl)-4,5-dihydro-2-oxazolyl]phenyl}benzenamine
95%
Synonym(s):
non-C2-symmetric bis(oxazoline) ligand
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About This Item
Empirical Formula (Hill Notation):
C25H31N3O2
CAS Number:
Molecular Weight:
405.53
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
InChI
1S/C25H31N3O2/c1-16(2)21-14-29-23(27-21)17-10-6-8-12-19(17)26-20-13-9-7-11-18(20)24-28-22(15-30-24)25(3,4)5/h6-13,16,21-22,26H,14-15H2,1-5H3/t21-,22-/m1/s1
SMILES string
CC(C)[C@H]1COC(=N1)c2ccccc2Nc3ccccc3C4=N[C@H](CO4)C(C)(C)C
InChI key
FIJNPJIMVUCDHH-FGZHOGPDSA-N
assay
95%
reaction suitability
reagent type: ligand
mp
92-96 °C
Application
Ligand for Chromium-Catalyzed Homoallenylation of Aldehydes.
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Angewandte Chemie (International Edition in English), 48, 1-5 (2009)
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