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Merck
CN

767905

4,4′-Dimethoxydiphenylamine

99%

Synonym(s):

4-Biphenylamine,4,4′-dimethoxy-, 4-Methoxy-N-(4-methoxyphenyl)aniline, p,p′-Dimethoxydiphenylamine, Benzenamine,4-methoxy-N-(4-methoxypheny)-, Bis(4-methoxyphenyl)-amine, Bis(4-methoxyphenyl)amine, Bis(p-anisyl)amine, Bis(p-methoxyphenyl)amine, Di-p-anisylamine, Di-p-methoxyphenylamine, Termofleks A

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About This Item

Empirical Formula (Hill Notation):
C14H15NO2
CAS Number:
101-70-2
Molecular Weight:
229.27
NACRES:
NA.23
PubChem Substance ID:
329767347
UNSPSC Code:
12352103
EC Number:
202-968-1
MDL number:
MFCD00014895

Key Documents

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Product Name

4,4′-Dimethoxydiphenylamine, 99%

InChI key

VCOONNWIINSFBA-UHFFFAOYSA-N

InChI

1S/C14H15NO2/c1-16-13-7-3-11(4-8-13)15-12-5-9-14(17-2)10-6-12/h3-10,15H,1-2H3

SMILES string

COc1ccc(Nc2ccc(OC)cc2)cc1

assay

99%

form

powder

mp

100-104 °C

Quality Level

100

Related Categories

Application

It can be used as a hole transporting material in the synthesis of 4,4′-dimethoxydiphenylamine-substituted 9,9′- bifluorenylidene with a power efficiency of ~18% which may be used in combination with an electron transporting layer in the fabrication of polymeric solar cells. It may also be used in the preparation of dimethyldiphenylamino functionalized carbazoles as electronically active materials which can potentially be used in the development of optoelectronic devices.

General description

4,4′-Dimethoxydiphenylamine is an aromatic amine that is used as a hole transporting material that facilitates efficiency mobility of charges in an electrochemical device.

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Warning

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCL3630
MKCC9432
MKBZ8321V
MKBZ5970V
MKBX7392V

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Thermally stable triaryl amino chromophores with high molecular hyperpolarizabilities
Spraul, Bryan K., et al.
Tetrahedron Letters, 45(16), 3253-3256 (2004)
Molecular-radical catalysis of the chain reaction of quinone imine with hydroquinone under the action of aromatic amines.
Varlamov VT.
Kinetics and Catalysis, 45(5), 662-675 (2004)
Triarylene linked spacer effect for dye-sensitized solar cells
Chang, Y. J., Wu, Y. J., Chou, P. T., Watanabe, M., & Chow, T. J.
Thin Solid Films, 558, 330-336 (2014)
Diphenylamino-substituted derivatives of 9-phenylcarbazole as glass-forming hole-transporting materials for solid state dye sensitized solar cells.
Tomkeviciene A, et al.
Synthetic Metals, 162(23), 1997-2004 (2012)
Dimethyldiphenylamino-substituted carbazoles as electronically active molecular materials.
Tomkeviciene A, et al.
Dyes and Pigments, 96(2), 574-580 (2013)
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