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Merck
CN

771171

2-Fluorophenylboronic acid MIDA ester

95%

Synonym(s):

2-(2-Fluorophenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

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About This Item

Empirical Formula (Hill Notation):
C11H11BFNO4
Molecular Weight:
251.02
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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assay

95%

form

solid

mp

160-165 °C

SMILES string

FC1=C(C=CC=C1)B2OC(CN(C)CC(O2)=O)=O

InChI

1S/C11H11BFNO4/c1-14-6-10(15)17-12(18-11(16)7-14)8-4-2-3-5-9(8)13/h2-5H,6-7H2,1H3

InChI key

XYOVDLHHSIQEEK-UHFFFAOYSA-N

Application

Protected boronic acid with methylimindodiacetic acid (MIDA) that does not react under standard Suzuki-Miyuara coupling conditions, allowing for selective and iterative cross-coupling sequences. The MIDA boronate also provides prolonged shelf life and stability to typically unstable boronic acid derivatives.

MIDA Boronates


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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