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Merck
CN

771228

2,4-Difluorophenylboronic acid MIDA ester

97%

Synonym(s):

2-(2,4-Difluorophenyl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione

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About This Item

Empirical Formula (Hill Notation):
C11H10BF2NO4
Molecular Weight:
269.01
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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form

solid

InChI

1S/C11H10BF2NO4/c1-15-5-10(16)18-12(19-11(17)6-15)8-3-2-7(13)4-9(8)14/h2-4H,5-6H2,1H3

SMILES string

O=C(CN(C)C1)OB(C2=C(F)C=C(F)C=C2)OC1=O

InChI key

AFNQHENRIQSJMU-UHFFFAOYSA-N

assay

97%

mp

199-201 °C

Application

Protected boronic acid with methylimindodiacetic acid (MIDA) that does not react under standard Suzuki-Miyuara coupling conditions, allowing for selective and iterative cross-coupling sequences. The MIDA boronate also provides prolonged shelf life and stability to typically unstable boronic acid derivatives.

MIDA Boronates

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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