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Merck
CN

771244

Sigma-Aldrich

Chloro{2,6-bis[(phenylseleno-Se)methyl]phenyl-C}palladium(II)

97%

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About This Item

Empirical Formula (Hill Notation):
C20H17ClPdSe2
CAS Number:
Molecular Weight:
557.14
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
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Assay

97%

form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

impurities

≤1% Dichloromethane

mp

162-221 °C

storage temp.

2-8°C

SMILES string

Cl[Pd]c1c(C[Se]c2ccccc2)cccc1C[Se]c3ccccc3

InChI

1S/C20H17Se2.ClH.Pd/c1-3-10-19(11-4-1)21-15-17-8-7-9-18(14-17)16-22-20-12-5-2-6-13-20;;/h1-13H,15-16H2;1H;/q;;+1/p-1

InChI key

UPTIBUSNQPQCIY-UHFFFAOYSA-M

Application

Application Statement: Complex promotes the formation of alpha-amino acids and allyl alcohols through a Petasis Borono-Mannich reaction.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - STOT RE 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Nicklas Selander et al.
Journal of the American Chemical Society, 129(44), 13723-13731 (2007-10-13)
An efficient one-pot procedure was designed by integration of the pincer-complex-catalyzed borylation of allyl alcohols in the Petasis borono-Mannich reaction and in allylation of aldehydes and ketones. These procedures are suitable for one-pot synthesis of alpha-amino acids and homoallyl alcohols

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