771309
9-Phenanthrenylboronic acid MIDA ester
Synonym(s):
6-Methyl-2-(9-phenanthrenyl)-1,3,6,2-dioxazaborocane-4,8-dione
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About This Item
Empirical Formula (Hill Notation):
C19H16BNO4
Molecular Weight:
333.15
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
SMILES string
O=C(CN(C)C1)OB(C2=C3C(C=CC=C3)=C4C(C=CC=C4)=C2)OC1=O
InChI
1S/C19H16BNO4/c1-21-11-18(22)24-20(25-19(23)12-21)17-10-13-6-2-3-7-14(13)15-8-4-5-9-16(15)17/h2-10H,11-12H2,1H3
InChI key
RBVTWBFBGYNXBV-UHFFFAOYSA-N
form
solid
mp
268-271 °C
Application
Protected boronic acid with methylimindodiacetic acid (MIDA) that does not react under standard Suzuki-Miyuara coupling conditions, allowing for selective and iterative cross-coupling sequences. The MIDA boronate also provides prolonged shelf life and stability to typically unstable boronic acid derivatives.
MIDA Boronates
MIDA Boronates
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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