771953
exo-5-Norbornene-2-methanol
≥99% (exo)
Synonym(s):
exo-5-Norbornenyl methyl alcohol
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About This Item
Empirical Formula (Hill Notation):
C8H12O
CAS Number:
Molecular Weight:
124.18
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12162002
MDL number:
Assay:
≥99% (exo)
Form:
liquid
InChI
1S/C8H12O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,6-9H,3-5H2/t6-,7+,8?/m0/s1
SMILES string
OCC1C[C@@H]2C[C@H]1C=C2
InChI key
LUMNWCHHXDUKFI-KJFJCRTCSA-N
assay
≥99% (exo)
form
liquid
refractive index
n20/D 1.499
bp
200-205/760 mmHg
density
1.030 at 25 °C
Quality Level
General description
Exo-5-Norbornene-2-methanol is a norbornene derivative which is widely used as a monomer in the synthesis of polynorbornenes by vinyl polymerisation or ring opening methathesis polymerisation (ROMP). They are also used as a monomer or an intermediate in the synthesis of photoresist materials. This material is also widely used as an intermediate in the synthesis of pharmaceutically and biologically active compounds.
Application
Used as a monomer in the synthesis of polynorbornenes by ring opening metathesis polymerisation.
Features and Benefits
- Produces polymers with high thermal stability and transparency which are useful for optical applications.
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Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
10 - Combustible liquids
wgk
WGK 3
flash_point_f
195.0 °F
flash_point_c
90.55 °C
Regulatory Information
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Stereo-Selective Synthesis of 5-Norbornene-2-exo-carboxylic Acid-Rapid Isomerization and Kinetically Selective Hydrolysis.
Kanao, M., Otake, A., Tsuchiya, K., & Ogino, K.
International Journal of Organic Chemistry, 2, 26-30 (2012)
Water-soluble polymers from acid-functionalized norbornenes
Lienkamp, K., Kins, C. F., Alfred, S. F., Madkour, A. E., & Tew, G. N.
Journal of Polymer Science Part A: Polymer Chemistry, 47(5), 1266-1273 (2009)
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