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Merck
CN

772550

Sigma-Aldrich

Poly(tert-butyl acrylate), DDMAT terminated

average Mn 7,000

Synonym(s):

Poly(tert-butyl acrylate), Poly(tert-butyl acrylate) RAFT

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About This Item

Linear Formula:
C4H7O2(C7H12O2)nC13H25S3
UNSPSC Code:
12352100
NACRES:
NA.23

Key Documents

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form

powder

mol wt

average Mn 7,000

transition temp

Tm 239-244 °C

PDI

<1.2

storage temp.

2-8°C

Application

Poly(tert-butyl acrylate) is a hydrophobic polymer used in many applications; primarily in which the tert-butyl group is substituted with a desired functionality. The end group functionality contains a carboxylic acid (COOH) as well as the 2-(Dodecylthiocarbonothioylthio)-2-methylpropionic acid RAFT agent moiety. This will allow for additional polymerization to generate a diblock copolymer. This RAFT agent is especially suited for the polymerization of styrene; acrylate and acrylamide monomers.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBN3784V

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Articles

Functional Polymers for Biomedical Apps

Microparticles in drug delivery: Study on controlling chitosan microparticle size and distribution, exploring encapsulation of BSA and TPP cross-linker.

Functional RAFT Polymers for Biomedical Applications

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

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