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Merck
CN

773808

Cyanomethyl [3-(trimethoxysilyl)propyl] trithiocarbonate

95% (GC)

Synonym(s):

Carbonotrithioic acid, Cyanomethyl 3-(trimethoxysilyl)propyl ester, clickable RAFT agent, silane RAFT agent, surface-initiated RAFT agent

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About This Item

Empirical Formula (Hill Notation):
C9H17NO3S3Si
CAS Number:
1050502-37-8
Molecular Weight:
311.52
MDL number:
MFCD24386382
UNSPSC Code:
12352100
PubChem Substance ID:
329767639
NACRES:
NA.23

Key Documents

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Assay

95% (GC)

form

liquid

refractive index

n20/D 1.553

density

1.219 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CO[Si](CCCSC(=S)SCC#N)(OC)OC

InChI

1S/C9H17NO3S3Si/c1-11-17(12-2,13-3)8-4-6-15-9(14)16-7-5-10/h4,6-8H2,1-3H3

InChI key

NGRLZFIXIPQVRW-UHFFFAOYSA-N

General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization
Silane functionalized RAFT agent for surface functionalization; RAFT reagent with a trimethoxysilyl group that can be attached to surfaces. Especially suited for the polymerization of styrene; acrylate and acrylamide monomers. Controlled radical polymerization; Chain Transfer Agent (CTA)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319,H335

Precautionary Statements

P261 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

12 - Non Combustible Liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCF6820
MKCD2922
MKBN3135

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Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

Articles

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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