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Merck
CN

774685

1-Dodecylmagnesium bromide solution

0.5 M in 2-methyltetrahydrofuran

Synonym(s):

Dodecylmagnesium bromide solution

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About This Item

Linear Formula:
CH3(CH2)11MgBr
CAS Number:
Molecular Weight:
273.54
UNSPSC Code:
12352103
PubChem Substance ID:
MDL number:
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form

solution

reaction suitability

reaction type: Grignard Reaction

concentration

0.5 M in 2-methyltetrahydrofuran

density

0.908 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCCCCCCCCCCC[Mg]Br

InChI

1S/C12H25.BrH.Mg/c1-3-5-7-9-11-12-10-8-6-4-2;;/h1,3-12H2,2H3;1H;/q;;+1/p-1

InChI key

JSDNASSZWGNUBO-UHFFFAOYSA-M

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Packaging

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC


signalword

Danger

supp_hazards

Storage Class

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 3

flash_point_f

6.8 °F

flash_point_c

-14 °C

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - Water-react. 2

Regulatory Information

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