775770
2-Bromobiphenyl-2′-boronic acid MIDA ester
97%
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About This Item
Empirical Formula (Hill Notation):
C17H15BBrNO4
Molecular Weight:
388.02
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C17H15BBrNO4/c1-20-10-16(21)23-18(24-17(22)11-20)14-8-4-2-6-12(14)13-7-3-5-9-15(13)19/h2-9H,10-11H2,1H3
SMILES string
O=C(CN(C)C1)OB(C2=C(C3=CC=CC=C3Br)C=CC=C2)OC1=O
InChI key
VYLANPHYJDQCQB-UHFFFAOYSA-N
assay
97%
form
solid
mp
275-280 °C
functional group
bromo
Application
Protected boronic acid with methylimindodiacetic acid (MIDA) that does not react under standard Suzuki-Miyuara coupling conditions, allowing for selective and iterative cross-coupling sequences. The MIDA boronate also provides prolonged shelf life and stability to typically unstable boronic acid derivatives.
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