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Merck
CN

776424

Poly(tert-butyl acrylate), DDMAT terminated, azide terminated

average Mn 8,500, PDI ≤1.2

Synonym(s):

poly(t-butyl acrylate) RAFT

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About This Item

NACRES:
NA.23
UNSPSC Code:
12352100

Key Documents

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form

solid

mol wt

average Mn 8,500

transition temp

Tm 241-246 °C

PDI

≤1.2

Application

Poly(tert-butyl acrylate) is a hydrophobic polymer used in many applications; primarily in which the tert-butyl group is substituted with a desired functionality. The hydrophilicity of this block can be tuned by varying the hydrolysis of the t-butyl group. The end group functionality contains an azide as well as the 2-(Dodecylthiocarbonothioylthio)-2-methylpropionic acid RAFT agent moiety. This RAFT CTA will allow for additional polymerization to generate a diblock copolymer. This RAFT agent is especially suited for the polymerization of styrene; acrylate and acrylamide monomers.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBR0320V
MKBN9468

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Articles

Functional Polymers for Biomedical Apps

Microparticles in drug delivery: Study on controlling chitosan microparticle size and distribution, exploring encapsulation of BSA and TPP cross-linker.

Functional RAFT Polymers for Biomedical Applications

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

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