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Merck
CN

776424

Sigma-Aldrich

Poly(tert-butyl acrylate), DDMAT terminated, azide terminated

average Mn 8,500, PDI ≤1.2

Synonym(s):

poly(t-butyl acrylate) RAFT

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About This Item

UNSPSC Code:
12352100
NACRES:
NA.23

Key Documents

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form

solid

mol wt

average Mn 8,500

transition temp

Tm 241-246 °C

PDI

≤1.2

Application

Poly(tert-butyl acrylate) is a hydrophobic polymer used in many applications; primarily in which the tert-butyl group is substituted with a desired functionality. The hydrophilicity of this block can be tuned by varying the hydrolysis of the t-butyl group. The end group functionality contains an azide as well as the 2-(Dodecylthiocarbonothioylthio)-2-methylpropionic acid RAFT agent moiety. This RAFT CTA will allow for additional polymerization to generate a diblock copolymer. This RAFT agent is especially suited for the polymerization of styrene; acrylate and acrylamide monomers.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBR0320V
MKBN9468

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Articles

Functional RAFT Polymers for Biomedical Applications

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

Functional Polymers for Biomedical Apps

Microparticles in drug delivery: Study on controlling chitosan microparticle size and distribution, exploring encapsulation of BSA and TPP cross-linker.

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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