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Merck
CN

777277

Sigma-Aldrich

1-(Phthalimidomethyl) 2-bromoisobutyrate

97%

Synonym(s):

ATRP initiator, protected amine BIB

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About This Item

Empirical Formula (Hill Notation):
C13H12BrNO4
CAS Number:
903562-13-0
Molecular Weight:
326.14
MDL number:
MFCD24849730
UNSPSC Code:
12162002
PubChem Substance ID:
329767896
NACRES:
NA.23

Key Documents

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Assay

97%

form

solid

mp

89-94 °C

storage temp.

2-8°C

SMILES string

CC(C)(Br)C(=O)OCN1C(=O)c2ccccc2C1=O

InChI

1S/C13H12BrNO4/c1-13(2,14)12(18)19-7-15-10(16)8-5-3-4-6-9(8)11(15)17/h3-6H,7H2,1-2H3

InChI key

AIPGWKMNUNTLCB-UHFFFAOYSA-N

Application

This ATRP initiator can be used to generate a polymer with a protected amine end group functionality.

Pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

Signal Word

Danger

Hazard Statements

H301,H315,H319,H335,H410

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBN9315

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Schroder; Kristin;
ACS Macro Letters, 1, 1037-1040 (2012)
Harry C Pappas et al.
ACS applied materials & interfaces, 7(50), 27632-27638 (2015-11-26)
Mitigation of bacterial adhesion and subsequent biofilm formation is quickly becoming a strategy for the prevention of hospital-acquired infections. We demonstrate a basic strategy for surface modification that combines the ability to control attachment by microbes with the ability to
Stefanie L Baker et al.
Biomacromolecules, 19(9), 3798-3813 (2018-08-08)
The power and elegance of protein-polymer conjugates has solved many vexing problems for society. Rational design of these complex covalent hybrids depends on a deep understanding of how polymer physicochemical properties impact the conjugate structure-function-dynamic relationships. We have generated a
Xiujun Ren et al.
Journal of chromatography. A, 1618, 460904-460904 (2020-01-30)
A novel chiral stationary phase (CSP) was prepared through the reaction of surface-initiated atom transfer radical polymerization (ATRP) by the copolymerization of thermoresponsive N-isopropylacrylamide (NIPAM) and β-cyclodextrin (β-CD) on the silica beads for high performance liquid chromatography (HPLC). X-ray photoelectron

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